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14. Patent Application no.: 128921                 16. Patent Application no.: 1063/CAL/1974
 Title: Improvements in or relating to                        Title: An improved method for

 methylenedioxyphenyl derivatives                         preparation of 1,1-di-(4-chlorophenyl)-2,
 Date of Filing: August 21, 1970                                  2,2-trichloroethanol
 Granted date: October 24, 1970                                Date of Filing: May 14, 1974
 Brief about technology: The invention relates to            Granted date: August 23, 1975
 Methylenedioxyphenyl derivatives which constitute     Brief about technology: The invention relates
 economical and efficient synergists for pyrethrins   to the preparationof 1,1-di-(4-chlorophenyl)-2,
 and particularly to methylenedioxyphenyl derivatives   2,2trichloroethanol commonly known as Dicofol
 containing at least a 3-carbon side chain on the    or Kelthane from 1,1-di-(4-cholorophenyl)-1, 2, 2,
 benzene nucleus, a methylenedioxy group at the 3, 4   2-tetracholoroethane for use as an acaricide and synergist
 positions and two methoxy groups at positions 5 and       for various type of DDT formulations.
 6 of the nucleus.









                                                       17. Patent Application no.: 1442/CAL/74

                                                   Title: Improvements in or relating to preparation of alpha-
                                                    substituted 3,4-methylenedioxycinnamoyl derivatives as
                                                                  synergists for pyrethrins
 15. Patent Application no.: 133090                             Date of Filing: June 27, 1954
 Title: Improvements in or relating to preparation
                                                               Granted date: October 11, 1975
 of 2, 2, 2-trichloro-1, 1-di-(4-chlorophenyl) ethanol  Brief about technology: This invention relates to
 Date of Filing: October 01, 1971                 methylenedioxyphenyl derivatives which constitutes a potent
 Granted date:  September 16, 1972                                  group synergists for
 Brief about technology: The invention               pyrethrins and carbamates and more particularly to the
 relates to preparation of 2, 2, 2 –trichloro       condensation products of an aromatic aldehyde bearing a
 1, 1-di (4-chlorophenyl) ethanol from 1,1-di       methylenedioxy function with reactive aliphatic carbonyl
 (4-cholorophenyl)-1, 2, 2, 2-tetrachloroethane for use   compounds such as aliphaticaldehydes or anhydrides to get the
 as an acaricide as well as a synergist for various types   desired cinnamoyl derivatives having alkyl (C1-C8) substituents
 of D.D.T formulations.                                           at the alpha carbon atom.















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