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14. Patent Application no.: 128921                                                                     16. Patent Application no.: 1063/CAL/1974
                                                                      Title: Improvements in or relating to                                                                        Title: An improved method for

                                                                       methylenedioxyphenyl derivatives                                                                        preparation of 1,1-di-(4-chlorophenyl)-2,
                                                                        Date of Filing: August 21, 1970                                                                                 2,2-trichloroethanol
                                                                        Granted date: October 24, 1970                                                                              Date of Filing: May 14, 1974
                                                                Brief about technology: The invention relates to                                                                   Granted date: August 23, 1975
                                                               Methylenedioxyphenyl derivatives which constitute                                                            Brief about technology: The invention relates
                                                                economical and efficient synergists for pyrethrins                                                          to the preparationof 1,1-di-(4-chlorophenyl)-2,
                                                              and particularly to methylenedioxyphenyl derivatives                                                         2,2trichloroethanol commonly known as Dicofol
                                                                 containing at least a 3-carbon side chain on the                                                         or Kelthane from 1,1-di-(4-cholorophenyl)-1, 2, 2,
                                                              benzene nucleus, a methylenedioxy group at the 3, 4                                                     2-tetracholoroethane for use as an acaricide and synergist
                                                              positions and two methoxy groups at positions 5 and                                                               for various type of DDT formulations.
                                                                               6 of the nucleus.









                                                                                                                                                                            17. Patent Application no.: 1442/CAL/74

                                                                                                                                                                         Title: Improvements in or relating to preparation of alpha-
                                                                                                                                                                          substituted 3,4-methylenedioxycinnamoyl derivatives as
                                                                                                                                                                                        synergists for pyrethrins
                                                                   15. Patent Application no.: 133090                                                                                Date of Filing: June 27, 1954
                                                               Title: Improvements in or relating to preparation
                                                                                                                                                                                    Granted date: October 11, 1975
                                                              of 2, 2, 2-trichloro-1, 1-di-(4-chlorophenyl) ethanol                                                         Brief about technology: This invention relates to
                                                                       Date of Filing: October 01, 1971                                                                methylenedioxyphenyl derivatives which constitutes a potent
                                                                     Granted date:  September 16, 1972                                                                                    group synergists for
                                                                    Brief about technology: The invention                                                                 pyrethrins and carbamates and more particularly to the
                                                                  relates to preparation of 2, 2, 2 –trichloro                                                           condensation products of an aromatic aldehyde bearing a
                                                                  1, 1-di (4-chlorophenyl) ethanol from 1,1-di                                                            methylenedioxy function with reactive aliphatic carbonyl
                                                             (4-cholorophenyl)-1, 2, 2, 2-tetrachloroethane for use                                                    compounds such as aliphaticaldehydes or anhydrides to get the
                                                             as an acaricide as well as a synergist for various types                                                  desired cinnamoyl derivatives having alkyl (C1-C8) substituents
                                                                            of D.D.T formulations.                                                                                     at the alpha carbon atom.















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